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Increased Cycling Efficiency of Lithium Anodes in Dimethyl Sulfoxide Electrolytes For Use in Li-O-2 Batteries

机译:用于Li-O-2电池的二甲基亚砜电解质中锂阳极的循环效率提高

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摘要

High lithium cycling efficiencies are required if a metal anode system is to be considered for use in Li-O-2 batteries. In this work electrolyte additives (0.3 M LiNO3 and 0.14 M VC) were used to increase the efficiency from 25 to 82.5% in the topical DMSO based electrolyte. Furthermore, we show that oxygen also acts to improve the cycling efficiency to 87%. This work highlights the importance of anode considerations in the development of metal O-2 batteries in alternative solvents (DMSO, Acetonitrile and DMA) and suggests realistic strategies for performance improvements. (C)The Author(s) 2014. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. All rights reserved.
机译:如果要考虑将金属阳极系统用于Li-O-2电池,则需要较高的锂循环效率。在这项工作中,使用电解质添加剂(0.3 M LiNO3和0.14 M VC)将局部DMSO基电解质的效率从25%提高到82.5%。此外,我们证明氧气还可以将循环效率提高到87%。这项工作强调了在替代溶剂(DMSO,乙腈和DMA)中开发金属O-2电池时考虑阳极的重要性,并提出了提高性能的现实策略。 (C)作者2014。由ECS出版。本文是根据知识共享署名4.0许可(CC BY,http://creativecommons.org/licenses/by/4.0/)的条款分发的开放获取文章,该文章允许在任何介质中无限制地重复使用该作品,正确引用了原始作品。版权所有。

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